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What is the Lewis theory of acids and bases?

The Lewis theory is the most general way to define acids and bases. Here’s a explanation:


1. Acid (Lewis)

  • A Lewis acid is a substance that accepts a pair of electrons.
  • Example:
    • BF₃ + NH₃ → F₃B–NH₃
      • BF₃ accepts an electron pair from NH₃ → acts as a Lewis acid

2. Base (Lewis)

  • A Lewis base is a substance that donates a pair of electrons.
  • Example:
    • NH₃ + H⁺ → NH₄⁺
      • NH₃ donates an electron pair to H⁺ → acts as a Lewis base

Key Points

  • Does not require H⁺ or OH⁻ ions.
  • Focuses on electron pair transfer, not just protons.
  • Includes more reactions than Arrhenius or Brønsted-Lowry definitions.

In short:

Lewis acid → takes electron pair
Lewis base → gives electron pair

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