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What is the standard hydrogen electrode (SHE)?

The Standard Hydrogen Electrode (SHE) is a reference electrode used in electrochemistry to measure the voltage of other electrodes. Its voltage is defined as 0 volts, so it acts like a baseline.


How it is made:

  • A platinum electrode is placed in an acidic solution.
  • Hydrogen gas is bubbled over the platinum.

How it works:

  • The electrode can either give or take electrons with hydrogen in the solution.
  • By connecting another electrode to the SHE, we can measure its voltage compared to this standard.

Conditions:

  • The hydrogen gas is at normal pressure.
  • The acid solution is at a standard concentration.
  • The temperature is room temperature.

Why it is important:

  • It helps determine the strength of other electrodes.
  • It is used in creating the electrochemical series.
  • It serves as a reference in many electrochemical experiments.

In simple words: SHE is like a “zero point” in electrochemistry that helps us compare how strong other electrodes are.

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