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What is the electronic configuration of diatomic oxygen (O₂) using MOT?

Here’s a explanation:

Diatomic oxygen (O₂) has 16 electrons. In Molecular Orbital Theory:

  • The electrons first fill the lower-energy orbitals (from 1s and 2s).
  • Then they fill the 2p orbitals.
  • In the 2p orbitals, two electrons are unpaired in the higher-energy anti-bonding orbitals.

These unpaired electrons explain why O₂ is paramagnetic (it is attracted to a magnetic field).

So simply: all lower orbitals are filled, and the two highest electrons are unpaired in molecular orbitals.

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