The standard electrode potential (E°) is a measure of the tendency of a chemical species to gain or lose electrons under standard conditions. In simpler terms, it tells us how easily a substance gets reduced or oxidized.
Key Points:
- Definition:
- It is the voltage of an electrode when it is connected to a standard hydrogen electrode (SHE) under standard conditions:
- 1 M concentration of ions
- 1 atm pressure for gases
- 25°C (298 K) temperature
- It is the voltage of an electrode when it is connected to a standard hydrogen electrode (SHE) under standard conditions:
- Sign Convention:
- Positive E°: The substance easily gains electrons (strong oxidizing agent).
- Negative E°: The substance loses electrons easily (strong reducing agent).
- Measurement:
- Measured by connecting the electrode to the standard hydrogen electrode and recording the potential difference.
- Applications:
- Predict the direction of redox reactions.
- Determine the feasibility of electrochemical reactions.
- Used in designing batteries and fuel cells.
In short: Standard electrode potential tells us how strongly a species wants to be reduced compared to hydrogen under standard conditions.