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What is the difference between a high-spin and low-spin complex?

Here’s a explanation:

High-spin complex:

  • Forms with weak ligands like Cl⁻ or F⁻.
  • Electrons stay unpaired as much as possible.
  • Has more unpaired electrons → more magnetic.

Low-spin complex:

  • Forms with strong ligands like CN⁻ or CO.
  • Electrons pair up in lower-energy orbitals first.
  • Has fewer unpaired electrons → less magnetic.

In short:

  • High-spin = more unpaired electrons
  • Low-spin = fewer unpaired electrons

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