Here’s a explanation:
- Crystal Field Theory (CFT) says that when ligands surround a metal ion, the metal’s d-orbitals split into different energy levels.
- Light absorption: Electrons in the lower-energy d-orbitals can jump to higher-energy d-orbitals if they absorb light of the right energy.
- Color: The metal complex shows the complementary color of the light it absorbs.
- Example: If it absorbs red light, it looks green.
- What affects the color:
- Type of metal and its charge
- Type of ligands (some ligands make bigger splitting)
- Shape of the complex (octahedral, tetrahedral, etc.)
In short: CFT explains the splitting of d-orbitals → electrons jump when they absorb light → the complex shows color.