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What is oxidative addition in organometallic chemistry?

Oxidative Addition

  • The metal breaks a bond in a molecule (like H–H or C–X).
  • Both pieces of that bond attach to the metal.
  • The metal ends up with more ligands and a higher oxidation state.

Example: A metal splits H₂ into two M–H bonds.


Reductive Elimination (opposite step)

  • Two groups on the metal join together and leave as a molecule (like H₂, CH₄, or R–R).
  • The metal has fewer ligands and a lower oxidation state.

Example: Two M–H bonds combine and release H₂.


In short:

  • Oxidative addition = metal grabs and splits a bond.
  • Reductive elimination = metal lets two groups go as a bond.

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