Here’s the simple version of the nucleophilic aromatic substitution (SNAr) mechanism:
Steps:
- Attack – A nucleophile (like –OH, –NH₂) attacks the carbon on the ring that has a leaving group (like –Cl).
- Intermediate – The ring becomes temporarily non-aromatic (called the Meisenheimer complex).
- Leaving group leaves – The halogen (–Cl, –Br, etc.) goes away.
- Aromatic ring returns – The product is the aromatic ring with the nucleophile attached.
In short:
Nucleophile comes in → temporary intermediate → leaving group goes out → aromaticity restored.