A homologous series is a group of organic compounds that:
- Have the same general formula (e.g., alkanes: CₙH₂ₙ₊₂, alkenes: CₙH₂ₙ).
- Differ by a constant unit — usually a –CH₂– group between successive members.
- Show similar chemical properties because they contain the same functional group.
- Show a gradual change in physical properties (like boiling point, melting point, solubility, density) as the molecular mass increases.
For example:
- The alkane series: methane (CH₄), ethane (C₂H₆), propane (C₃H₈), butane (C₄H₁₀) …
Each member differs from the next by –CH₂–.
In short: A homologous series is a “family” of organic compounds with the same functional group, similar chemistry, and a regular difference in structure.