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What is an indicator in a titration?

An indicator in a titration is a substance that signals the end of a chemical reaction by changing color. It helps determine the endpoint—the point at which the reaction between the titrant and the analyte is complete.

Key Points:

  1. Purpose: To show visually when the titration is complete.
  2. How it Works:
    • Indicators change color depending on the pH (for acid-base titrations) or the chemical environment.
    • The color change occurs very close to the equivalence point, where the amount of titrant added is stoichiometrically equal to the substance in the flask.
  3. Examples of Indicators:
    • Phenolphthalein: Colorless in acid, pink in base (used in strong acid vs strong base titrations).
    • Methyl orange: Red in acid, yellow in base (used in strong acid vs weak base titrations).
    • Bromothymol blue: Yellow in acid, blue in base, green at neutral.
  4. Selection of Indicator: Depends on the type of reaction and the pH at equivalence point. Choosing the wrong indicator can give inaccurate results.

In short: An indicator is a visual “signal” that tells you when the titration is complete.

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