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What are the different types of intermolecular forces?

The different types of intermolecular forces (IMFs) are:

  1. London Dispersion Forces (Van der Waals forces)
    • Weakest type of force.
    • Present in all molecules (polar and non-polar).
    • Caused by temporary (instantaneous) shifts in electron clouds that create temporary dipoles.
    • Strength increases with larger molecules and more electrons.
  2. Dipole–Dipole Forces
    • Occur between molecules that have a permanent dipole (polar molecules).
    • Positive end of one molecule attracts the negative end of another.
    • Stronger than dispersion forces but weaker than hydrogen bonds.
  3. Hydrogen Bonding
    • A special, strong type of dipole–dipole interaction.
    • Happens when hydrogen is covalently bonded to a highly electronegative atom (N, O, or F) and is attracted to a lone pair on another molecule.
    • Responsible for properties of water like high boiling point and surface tension.
  4. Ion–Dipole Forces
    • Occur between ions and polar molecules.
    • Important in solutions, e.g., when salt (NaCl) dissolves in water.
    • Stronger than dipole–dipole and hydrogen bonds.

In summary:

  • London dispersion → weakest, in all molecules.
  • Dipole–dipole → in polar molecules.
  • Hydrogen bond → strong dipole force with H–N, H–O, or H–F.
  • Ion–dipole → strongest, between ions and polar molecules.

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