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What is Avogadro’s Law?

Avogadro’s Law is a fundamental principle in chemistry that describes the relationship between the volume of a gas and the number of gas particles (moles) when temperature and pressure are kept constant. It states:

“Equal volumes of all gases, at the same temperature and pressure, contain the same number of molecules.”

In simpler terms:

  • If you increase the number of gas particles, the volume increases proportionally, as long as temperature and pressure do not change.
  • Conversely, if you decrease the number of gas particles, the volume decreases proportionally.

Mathematically, it is expressed as: V∝n

where:

  • V = volume of the gas
  • n = number of moles of the gas

Key points to remember:

  1. Temperature and pressure must remain constant.
  2. It explains why gases expand to fill their containers.
  3. It is the basis for understanding the molar volume of a gas, which is 22.4 liters at standard temperature and pressure (STP).

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