The order of a reaction tells us how the rate of a chemical reaction depends on the concentration of reactants.
Key points:
- Definition:
- For a reaction aA + bB → products, if the rate law is Rate = k [A]^m [B]^n,
- m = order with respect to A
- n = order with respect to B
- Overall order = m + n
- For a reaction aA + bB → products, if the rate law is Rate = k [A]^m [B]^n,
- Interpretation:
- m = 1: Rate is directly proportional to [A] (first order with respect to A).
- m = 2: Rate is proportional to [A]² (second order with respect to A).
- m = 0: Rate is independent of [A] (zero order).
- Determination:
- Reaction order is determined experimentally, not from the balanced equation.
- Significance:
- Helps understand reaction kinetics and predict how changing concentrations affects the rate.
In short: The order of a reaction is the exponent of reactant concentration in the rate law, indicating how strongly that reactant affects the reaction speed.