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What is the order of a reaction?

The order of a reaction tells us how the rate of a chemical reaction depends on the concentration of reactants.

Key points:

  1. Definition:
    • For a reaction aA + bB → products, if the rate law is Rate = k [A]^m [B]^n,
      • m = order with respect to A
      • n = order with respect to B
      • Overall order = m + n
  2. Interpretation:
    • m = 1: Rate is directly proportional to [A] (first order with respect to A).
    • m = 2: Rate is proportional to [A]² (second order with respect to A).
    • m = 0: Rate is independent of [A] (zero order).
  3. Determination:
    • Reaction order is determined experimentally, not from the balanced equation.
  4. Significance:
    • Helps understand reaction kinetics and predict how changing concentrations affects the rate.

In short: The order of a reaction is the exponent of reactant concentration in the rate law, indicating how strongly that reactant affects the reaction speed.

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