Actinides exhibit multiple oxidation states mainly because their 5f, 6d, and 7s electrons are close in energy and can all participate in bonding.
Explanation in simple terms:
- The energy difference between these orbitals is small, so electrons can be lost from different shells.
- This allows actinides to form various ions with different charges.
- As a result, actinides show oxidation states ranging from +3 to +6 (sometimes +7) depending on the element and chemical environment.
Example:
- Uranium can exist as U³⁺, U⁴⁺, U⁵⁺, and U⁶⁺.
- Thorium mainly shows Th⁴⁺, but other actinides have multiple states.
In short: Multiple oxidation states happen because f, d, and s electrons are all available for bonding.