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What is the difference between a coordination complex and a complex ion?

Here’s a explanation:


Coordination Complex

  • A coordination complex is a metal with ligands attached.
  • It can be neutral or charged.
  • Example: [Co(NH₃)₆]Cl₃ → the part [Co(NH₃)₆] is the coordination complex.

Complex Ion

  • A complex ion is a metal with ligands that has a charge.
  • Example: [Fe(CN)₆]³⁻ → this is a complex ion because it has a –3 charge.

Simple way to remember:

  • Coordination complex → metal + ligands (may be neutral)
  • Complex ion → metal + ligands (always charged)

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