Alkaline earth metals are the elements of Group 2 in the periodic table (Be, Mg, Ca, Sr, Ba, Ra). They share several common physical and chemical properties:
General Properties of Alkaline Earth Metals
- Position in Periodic Table
- Found in Group 2.
- Valence shell configuration: ns².
- Examples: Beryllium (Be), Magnesium (Mg), Calcium (Ca), Strontium (Sr), Barium (Ba), Radium (Ra).
Physical Properties
- Appearance – Silvery-white, shiny metals.
- Hardness – Harder than alkali metals but softer than most transition metals.
- Density – Denser than alkali metals (except calcium, which is less dense than expected).
- Melting & Boiling Points – Higher than alkali metals of the same period but decrease down the group.
- Conductivity – Good conductors of heat and electricity due to metallic bonding.
Chemical Properties
- Reactivity – Less reactive than alkali metals but still highly reactive; reactivity increases down the group.
- Oxidation State – Show a stable +2 oxidation state by losing two valence electrons.
- Reaction with Oxygen – Form oxides (MO), which are basic in nature.
- Example: 2Mg + O₂ → 2MgO
- Reaction with Water –
- Be: does not react with water.
- Mg: reacts slowly with hot water.
- Ca, Sr, Ba, Ra: react readily with cold water, releasing H₂ gas.
- Reaction with Acids – React vigorously with dilute acids to form salts and release hydrogen gas.
- Example: Mg + 2HCl → MgCl₂ + H₂↑
- Reaction with Halogens – Combine directly to form ionic halides (MX₂).
- Compounds – Their compounds (oxides, hydroxides, carbonates, sulfates) are generally ionic, white, and less soluble in water (solubility decreases down the group, except hydroxides, which become more soluble).
Trends Down the Group
- Atomic & Ionic Size → Increases.
- Ionization Energy → Decreases.
- Electronegativity → Slightly decreases.
- Reactivity with water → Increases.
- Thermal stability of carbonates & nitrates → Increases down the group.
In short: Alkaline earth metals are shiny, moderately reactive metals with +2 oxidation state, forming ionic, basic compounds. Reactivity and metallic character increase from Be to Ra.