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What is energy-dispersive X-ray spectroscopy (EDS) used for in microanalysis?

Energy-Dispersive X-ray Spectroscopy (EDS or EDX) is a technique used in microanalysis to determine which elements are present in a very small sample and sometimes their approximate amounts.


How EDS Works:

  1. A sample is bombarded with high-energy electrons (usually from a Scanning Electron Microscope, SEM).
  2. These electrons knock inner-shell electrons out of atoms in the sample.
  3. When outer-shell electrons fall into the empty spots, they emit X-rays.
  4. Each element emits X-rays with characteristic energies, acting like a “fingerprint” for that element.

What EDS is Used for:

  1. Element Identification
    • Detects which elements (like C, O, Na, Fe, etc.) are present in a tiny area of a sample.
  2. Elemental Mapping
    • Shows how different elements are distributed across the surface of a sample.
  3. Quantitative Analysis
    • Estimates the relative amounts of elements in the sample (in percent).
  4. Microanalysis Applications
    • Materials science: Checking alloy composition or surface coatings.
    • Forensics: Analyzing tiny paint chips or glass fragments.
    • Environmental studies: Detecting pollutants in dust or soil particles.
    • Pharmaceuticals: Studying impurities in drugs or tablets.

In short:

EDS is used in microanalysis to identify and measure elements in very small samples, often in combination with SEM, giving both structural and compositional information.

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