The f-block elements (lanthanides and actinides) are called inner transition metals because:
- Position of filling – In these elements, the extra electrons go into the inner f-orbitals (4f in lanthanides, 5f in actinides) instead of the outer shells. That means the “transition” is happening deep inside the atom, not just in the outer layers.
- Placed inside the periodic table – They actually belong to period 6 and 7 of the table, but are usually shown separately at the bottom. If placed properly, they would fit inside the main body of the transition metals (between group 3 and group 4).
- Similar properties to transition metals – Like d-block transition metals, they:
- Show variable oxidation states
- Form colored ions
- Often show magnetic properties
- Can act as catalysts
But since the electrons are filling the inner f-orbitals, not the d-orbitals, they are called inner transition metals.
In short:
They are called inner transition metals because their f-orbitals (inner shells) are being filled, while they behave like transition metals in many ways.