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What types of detectors are used in HPLC?

Here is a explanation without any symbols or logos:


Types of Detectors Used in HPLC

1. UV-Visible (UV-Vis) Detector

  • The most common type of detector.
  • It measures how much ultraviolet or visible light a compound absorbs.
  • Useful for compounds that absorb UV light, such as many organic molecules and drugs.

2. Photodiode Array (PDA) Detector

  • A special type of UV detector that measures light at many wavelengths at the same time.
  • Helps to identify compounds by their full absorption spectrum.
  • Good for analyzing mixtures with several different compounds.

3. Refractive Index (RI) Detector

  • Measures changes in how light bends when different compounds pass through.
  • Works for compounds that do not absorb UV light.
  • Commonly used for sugars, alcohols, and polymers.

4. Fluorescence Detector

  • Detects compounds that give off light (fluoresce) when they are excited by a specific wavelength.
  • Very sensitive and selective.
  • Used for compounds such as vitamins, proteins, and certain drugs.

5. Conductivity Detector

  • Measures the electrical conductivity of the mobile phase as compounds come out of the column.
  • Mostly used in ion chromatography to detect ionic substances like salts or acids.

6. Electrochemical Detector

  • Detects compounds that can be oxidized or reduced by measuring electrical current changes.
  • Highly sensitive.
  • Commonly used for biological molecules and pharmaceuticals.

7. Mass Spectrometric (MS) Detector

  • Measures the mass-to-charge ratio of ions.
  • Gives both identification and quantity of compounds.
  • Used in LC-MS systems for drug, food, and environmental analysis.

In short:

  • UV-Vis and PDA detect light absorption.
  • RI detects refractive index changes.
  • Fluorescence detects emitted light.
  • Conductivity and electrochemical detectors sense electrical changes.
  • MS detects the mass of molecules.

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