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What is the role of the stationary phase in GC?

The stationary phase in Gas Chromatography (GC) is the material inside the column that helps to separate the compounds in a mixture.


Simple explanation:

  • The stationary phase can be a liquid coated on a solid support (in packed columns) or a thin film on the inner wall (in capillary columns).
  • As the sample moves through the column with the carrier gas, each compound interacts differently with the stationary phase.
    • Compounds that stick more strongly to the stationary phase move slowly.
    • Compounds that stick less move faster.
  • Because of these differences, the compounds separate and come out at different times (called retention times).

In short:

The stationary phase controls how long each compound stays in the column — it is the key part that separates the mixture based on each compound’s interaction and boiling point.

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