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What is the role of a standard solution in volumetric analysis?

A standard solution plays a very important role in volumetric analysis because it has a known and accurate concentration. It is used to determine the concentration of an unknown solution.


Roles of a Standard Solution:

  1. Reference for measurement:
    • It serves as a benchmark to compare against the unknown solution.
  2. Accurate calculation of unknown concentration:
    • By measuring the volume of the standard solution needed to react completely with the analyte, the concentration of the unknown can be calculated using stoichiometry.
  3. Ensures precision and reliability:
    • Using a standard solution reduces errors and improves the accuracy of titration results.
  4. Types of standard solutions:
    • Primary standard: Very pure, stable, and can be weighed accurately (e.g., sodium carbonate, potassium hydrogen phthalate).
    • Secondary standard: Standardized against a primary standard when a primary standard is not available (e.g., hydrochloric acid, sodium hydroxide).

In short:
A standard solution is a solution of known concentration used as a reference in titrations to determine the concentration of unknown solutions accurately.

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