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What are wave functions in quantum chemistry?

In quantum chemistry, a wave function is a mathematical function that describes the state of a particle, such as an electron in an atom or molecule.

Think of it as a “map” that contains all the information about the particle.

Key points:

  • The wave function is usually written as Ψ (psi).
  • It doesn’t directly give us the position of the particle. Instead, Ψ² (psi squared) tells us the probability of finding the particle at a certain place.
  • It can also describe other properties like energy, momentum, or spin.

Why it’s important in chemistry:

  • Wave functions explain how electrons are arranged in atoms and molecules.
  • They are used to understand chemical bonds, molecular shapes, and reactions.
  • Quantum chemistry calculations (like molecular orbital theory) are based on wave functions.

In short: A wave function is the “heart” of quantum mechanics, giving us the probability picture of where particles like electrons are likely to be.

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