Here’s a explanation:
Internal Energy (U)
- Definition: Internal energy is the total energy contained within a system.
- It includes:
- Kinetic energy of molecules (movement of particles)
- Potential energy of molecules (energy due to interactions between particles)
- It does not include energy from the system moving as a whole—only energy inside the system counts.
Why is Internal Energy Important?
- Measures the energy of a system:
- It tells us how much energy the molecules inside the system have.
- Relates to heat and work:
- When a system absorbs heat or does work, its internal energy changes.
- ΔU = Heat added to the system – Work done by the system
- Helps predict chemical and physical changes:
- Reactions, phase changes, and other processes involve changes in internal energy.
- State function:
- Only the initial and final energy matter, not the path taken.
Example:
- Boiling water: Heat increases the water molecules’ movement → internal energy rises.
- Compressed gas: Work done on the gas → internal energy increases.