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How are carbohydrates structurally classified?

Carbohydrates are structurally classified based on the number of sugar units they contain.

1. Monosaccharides (simple sugars)

  • Single sugar unit.
  • Cannot be hydrolyzed into simpler sugars.
  • Examples: Glucose, Fructose, Galactose.
  • Can be further classified by carbon atoms:
    • Trioses (3C), Pentoses (5C), Hexoses (6C)
  • Also by functional group:
    • Aldoses (with aldehyde group), Ketoses (with ketone group)

2. Disaccharides

  • Two monosaccharides linked by a glycosidic bond.
  • Formed by condensation reaction (loss of water).
  • Examples: Sucrose (glucose + fructose), Maltose (glucose + glucose), Lactose (glucose + galactose)

3. Oligosaccharides

  • Contain 3–10 monosaccharide units.
  • Often attached to proteins or lipids on cell surfaces for recognition.
  • Examples: Raffinose, Stachyose

4. Polysaccharides (complex carbohydrates)

  • Many monosaccharide units linked together.
  • Can be linear or branched.
  • Serve as energy storage or structural support.
  • Examples:
    • Energy storage: Starch (plants), Glycogen (animals)
    • Structural: Cellulose (plants), Chitin (insects/fungi)

In short:
Carbohydrates are classified as monosaccharides, disaccharides, oligosaccharides, and polysaccharides based on the number of sugar units and their complexity.

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