The different types of intermolecular forces (IMFs) are:
- London Dispersion Forces (Van der Waals forces)
- Weakest type of force.
- Present in all molecules (polar and non-polar).
- Caused by temporary (instantaneous) shifts in electron clouds that create temporary dipoles.
- Strength increases with larger molecules and more electrons.
- Dipole–Dipole Forces
- Occur between molecules that have a permanent dipole (polar molecules).
- Positive end of one molecule attracts the negative end of another.
- Stronger than dispersion forces but weaker than hydrogen bonds.
- Hydrogen Bonding
- A special, strong type of dipole–dipole interaction.
- Happens when hydrogen is covalently bonded to a highly electronegative atom (N, O, or F) and is attracted to a lone pair on another molecule.
- Responsible for properties of water like high boiling point and surface tension.
- Ion–Dipole Forces
- Occur between ions and polar molecules.
- Important in solutions, e.g., when salt (NaCl) dissolves in water.
- Stronger than dipole–dipole and hydrogen bonds.
In summary:
- London dispersion → weakest, in all molecules.
- Dipole–dipole → in polar molecules.
- Hydrogen bond → strong dipole force with H–N, H–O, or H–F.
- Ion–dipole → strongest, between ions and polar molecules.