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What are unimolecular and bimolecular reactions?

Here’s a explanation without equations:


1. Unimolecular Reaction

  • In this reaction, only one molecule is involved in the reaction step.
  • The molecule breaks down or rearranges itself to form products.
  • The reaction speed depends on the amount of that one molecule.
  • Example: Some gases naturally decompose on their own over time.

2. Bimolecular Reaction

  • In this reaction, two molecules collide and react together.
  • The reaction happens when the molecules meet with enough energy and correct orientation.
  • The reaction speed depends on the amount of both molecules.
  • Example: Hydrogen and iodine reacting to form hydrogen iodide (in general terms, two molecules react to form something new).

Simple idea:

  • Unimolecular = one molecule changes by itself
  • Bimolecular = two molecules must collide to react

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