Ionic solids are solids made up of positive and negative ions held together by strong electrostatic forces (ionic bonds).
Properties of Ionic Solids:
- Bonding
- Ions are arranged in a regular 3D lattice and held by strong ionic bonds.
- Hardness and Brittleness
- They are hard due to strong bonding, but also brittle (shatter when force is applied) because like charges may be forced close together.
- Melting and Boiling Points
- High melting and boiling points since strong forces need a lot of energy to break.
- Electrical Conductivity
- Do not conduct electricity in solid state (ions are fixed).
- Conduct electricity in molten state or aqueous solution (ions are free to move).
- Solubility
- Generally soluble in polar solvents like water, but insoluble in non-polar solvents.
- Examples
- Sodium chloride (NaCl), Potassium bromide (KBr), Magnesium oxide (MgO), Calcium fluoride (CaFâ‚‚).