The enthalpy change (ΔH) is the amount of heat absorbed or released by a reaction at constant pressure.
How to calculate it (without using equations):
- Using bond energies:
- Determine how much energy is required to break the bonds in the reactants.
- Determine how much energy is released when new bonds form in the products.
- Subtract the energy released from the energy absorbed to find the enthalpy change.
- Using standard enthalpies of formation:
- Look up the standard enthalpy values for all reactants and products.
- Compare the total energy of products with the total energy of reactants.
- The difference gives the enthalpy change.
- Using calorimetry (experimentally):
- Measure the temperature change of the solution or reaction mixture.
- Combine it with the mass and specific heat of the substance.
- This allows calculation of the heat absorbed or released, which is the enthalpy change.
Key idea:
- If the reaction absorbs heat, it is endothermic.
- If the reaction releases heat, it is exothermic.