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How do you calculate enthalpy change (ΔH)?

The enthalpy change (ΔH) is the amount of heat absorbed or released by a reaction at constant pressure.

How to calculate it (without using equations):

  1. Using bond energies:
    • Determine how much energy is required to break the bonds in the reactants.
    • Determine how much energy is released when new bonds form in the products.
    • Subtract the energy released from the energy absorbed to find the enthalpy change.
  2. Using standard enthalpies of formation:
    • Look up the standard enthalpy values for all reactants and products.
    • Compare the total energy of products with the total energy of reactants.
    • The difference gives the enthalpy change.
  3. Using calorimetry (experimentally):
    • Measure the temperature change of the solution or reaction mixture.
    • Combine it with the mass and specific heat of the substance.
    • This allows calculation of the heat absorbed or released, which is the enthalpy change.

Key idea:

  • If the reaction absorbs heat, it is endothermic.
  • If the reaction releases heat, it is exothermic.

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