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What is the difference between strong field and weak field ligands in LFT?

Weak-Field Ligands

  • Make small splitting of metal d-orbitals.
  • Usually give high-spin complexes (more unpaired electrons).
  • Bond is mostly ionic.
  • Examples: H₂O, OH⁻, Cl⁻

Strong-Field Ligands

  • Make large splitting of metal d-orbitals.
  • Usually give low-spin complexes (fewer unpaired electrons).
  • Bond is more covalent.
  • Examples: CN⁻, CO, NH₃

Simple Way to Remember

  • Weak-field → high-spin → small splitting → more unpaired electrons
  • Strong-field → low-spin → large splitting → fewer unpaired electrons

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